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Hydrogen s-Block and p-Block Elements formulas for JEE Main & Advanced

13 formula entries for Hydrogen s-Block and p-Block Elements, in the order the chapter builds them. Each shows the formula, when to use it and the first trap to avoid.

Water Gas Shift Reaction

CO+H2O→catalystCO2+H2

When to use. When solving problems on industrial hydrogen production or thermochemical cycles.

Trap. The catalyst is usually iron oxide or chromium oxide, not just any metal.

Hardness of Water Removal

Ca(HCO3)2→ΔCaCO3↓+H2O+CO2

When to use. When solving water treatment problems or distinguishing between hardness types.

Trap. Boiling only removes temporary hardness, not permanent.

Reaction of Alkali Metals with Water

2M+2H2O→2MOH+H2↑

When to use. When writing equations for alkali metal reactions or predicting products.

Trap. Lithium does not produce a flame; sodium produces a yellow flame; potassium produces a lilac flame.

Thermal Decomposition of Carbonates

MCO3→ΔMO+CO2↑

When to use. When predicting products of heating metal carbonates or comparing thermal stability.

Trap. BeCO₃ is unstable and decomposes at ~100°C, while BaCO₃ requires >1000°C.

Preparation of Borax (Na₂B₄O₇·10H₂O)

Ca2B6O11+2Na2CO3→Na2B4O7+2CaCO3↓+2NaBO2

When to use. When writing industrial preparation of boron compounds or in qualitative analysis.

Trap. The product is not pure borax; sodium metaborate (NaBO₂) is a byproduct.

Silicones

R2SiCl2+H2O→R2Si(OH)2→polymerization(R2SiO)n

When to use. When discussing polymer chemistry or applications of silicon compounds.

Trap. Silicones are not based on carbon; they have Si-O bonds, not C-C.

Reaction of Silicon with Alkali

Si+2NaOH+H2O→Na2SiO3+2H2↑

When to use. When writing reactions of silicon or comparing with carbon (which does not react with alkali).

Trap. Silicon does not react with acids (except HF), but reacts with alkalis.

Borax Bead Test

Na2B4O7→Δ2NaBO2+B2O3

When to use. When identifying metal ions in qualitative analysis.

Trap. The bead is tested in both oxidizing and reducing flames, and colours depend on the flame (e.g. Fe: yellow-brown oxidizing, green reducing).

Reaction of Ammonia with Chlorine

8NH3+3Cl2→6NH4Cl+N2 (excess NH₃; the HCl formed is taken up as NH₄Cl) NH3+3Cl2→NCl3+3HCl (excess Cl₂)

When to use. When predicting products of ammonia reactions or in industrial chemistry.

Trap. NCl₃ is explosive, not stable.

Ostwald's Process for HNO₃

4NH3+5O2→Pt/Rh4NO+6H2O 2NO+O2→2NO2 3NO2+H2O→2HNO3+NO

When to use. When solving industrial chemistry problems or writing the process steps.

Trap. The catalyst is Pt/Rh, not just platinum.

Sulfuric Acid: Contact Process

S+O2→SO2 2SO2+O2→V2O52SO3 SO3+H2SO4→H2S2O7 (oleum) H2S2O7+H2O→2H2SO4

Trap. SO₃ is not absorbed in water directly (forms a mist); it is absorbed in H₂SO₄.

Reaction of Halogens with Water

X2+H2O→HX+HOX (for Cl₂, Br₂) 2F2+2H2O→4HF+O2

When to use. When writing reactions of halogens or comparing their oxidizing power.

Trap. Fluorine gives O₂, not HOCl, due to high oxidizing power.

Interhalogen Compounds

Cl2+3F2→2ClF3

When to use. When predicting structures or reactions of halogen compounds.

Trap. The central atom is always the larger halogen (lower electronegativity).

Values to remember

  • 1312 kJ/mol Position of Hydrogen
  • 1 Isotopes of Hydrogen
  • 2 Isotopes of Hydrogen
  • 3 Isotopes of Hydrogen
  • 520 kJ/mol (Li) Alkali Metals (Group 1) General Trends
  • 496 kJ/mol (Na) Alkali Metals (Group 1) General Trends
  • 419 kJ/mol (K) Alkali Metals (Group 1) General Trends
  • 899 kJ/mol (Be) Alkaline Earth Metals (Group 2) General Trends
  • 738 kJ/mol (Mg) Alkaline Earth Metals (Group 2) General Trends
  • 590 kJ/mol (Ca) Alkaline Earth Metals (Group 2) General Trends
  • 500 K (Pt/Rh gauze) Ostwald's Process for HNO₃
  • 9 bar Ostwald's Process for HNO₃
  • 96∘C Sulfur Allotropes
  • 450∘C Sulfuric Acid: Contact Process

Read the full chapter: Hydrogen s-Block and p-Block Elements for JEE, with what JEE asks and the common traps.